N2.3−: Filling a Gap in the N2n− Series
Identifieur interne : 001168 ( Main/Exploration ); précédent : 001167; suivant : 001169N2.3−: Filling a Gap in the N2n− Series
Auteurs : Wolfgang Kaim [Allemagne] ; Biprajit Sarkar [Allemagne]Source :
- Angewandte Chemie International Edition [ 1433-7851 ] ; 2009-12-07.
English descriptors
- Teeft :
- Angew, Bond length, Chem, Dalton trans, Inorg, Kaim, Ligand, Sarkar, Verlag gmbh, Weinheim.
Abstract
The unexpected stability of the exotic N2.3− species has been observed in its complexes with Dy3+ and Y3+. The three‐electron reduction product of N2 is isoelectronic with superoxide O2.− (see scheme) and is a possible bound intermediate in the conversion of N2 into NH3.
Url:
DOI: 10.1002/anie.200904968
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Istex, to step Corpus: 000738
- to stream Istex, to step Curation: 000738
- to stream Istex, to step Checkpoint: 000286
- to stream Main, to step Merge: 001178
- to stream Main, to step Curation: 001168
Le document en format XML
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<front><div type="abstract" xml:lang="en">The unexpected stability of the exotic N2.3− species has been observed in its complexes with Dy3+ and Y3+. The three‐electron reduction product of N2 is isoelectronic with superoxide O2.− (see scheme) and is a possible bound intermediate in the conversion of N2 into NH3.</div>
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